we can use the clausius clapeyron equation to solve this
.. ln(P1 / P2) = (dHvap / R) x (1/T2 - 1/T1)
note we're given P1, P2, T1, T2 and P3 and asked to find T3.
so if we assume dHvap and R are constants, we can write
.. ln(P1 / P3) = (dHvap / R) x (1/T3 - 1/T1)
now.. you can manipulate those equations and cancel out dHvap/R to generate
1 equation in terms of P1, P2, P3, T1, T2, and T3.. . or if you prefer, you could
just solve for dHvap.R in the first equation, and carry that over to the 2nd.
let's do that
.. (dHvap/R) = ln(P1 / 2P1) / (1/375.15 - 1/264.15) =
.. ... ... .. ... .= ln(1 / 2) / (1/375.15K - 1/264.15K)
.. .... ... ... ...= 8608.3 K
plugging that into the 2nd
.. 1/T3 = 1/T1 + ln(P1 / P3) / (dHvap/R)
.. 1/T3 = 1/364.15K + ln(1/6) / (8608.3K)
.. . ..T3 = 394.0K = 121°C
Copyright © 2024 1QUIZZ.COM - All rights reserved.
Answers & Comments
we can use the clausius clapeyron equation to solve this
.. ln(P1 / P2) = (dHvap / R) x (1/T2 - 1/T1)
note we're given P1, P2, T1, T2 and P3 and asked to find T3.
so if we assume dHvap and R are constants, we can write
.. ln(P1 / P2) = (dHvap / R) x (1/T2 - 1/T1)
.. ln(P1 / P3) = (dHvap / R) x (1/T3 - 1/T1)
now.. you can manipulate those equations and cancel out dHvap/R to generate
1 equation in terms of P1, P2, P3, T1, T2, and T3.. . or if you prefer, you could
just solve for dHvap.R in the first equation, and carry that over to the 2nd.
let's do that
.. (dHvap/R) = ln(P1 / 2P1) / (1/375.15 - 1/264.15) =
.. ... ... .. ... .= ln(1 / 2) / (1/375.15K - 1/264.15K)
.. .... ... ... ...= 8608.3 K
plugging that into the 2nd
.. 1/T3 = 1/T1 + ln(P1 / P3) / (dHvap/R)
.. 1/T3 = 1/364.15K + ln(1/6) / (8608.3K)
.. . ..T3 = 394.0K = 121°C