The Ka of a monoprotic weak acid is 5.81 × 10-3. What is the percent ionization of a 0.111 M solution of this acid?
My calculations:
Ka= 5.81x10^-3=x^2/0.111---> x^2= (5.81x10^-3)(0.111)---->x^2=6.4991x10^-4----> x= 0.0254
Percent Ionization= (0.0254/0.111)x100%= 22.88%
As you can see I was only able to solve this halfway through. It's not valid because it's more than 5% so I have to use the quadratic formula. Problem is I don't know what values to place as a,b, or c for the quadratic formula. Can anyone please help me with this. The best explanation gets 10 points!
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Answers & Comments
Verified answer
5.81e-3 = x*x / 0.111-x
6.449e-4 - 5.81e-3x - x^2 = 0
A = -1
B = -5.81e-3
C = +6.449e-4
Plug it in the quadratic equation formula
x = 0.022655
% Ionization = (0.022655/0.111) * 100 = 20.41%
So not much difference. Your method is correct
Read up on some info about Quadratic Formula
http://en.wikipedia.org/wiki/Quadratic_equation
anticipate a susceptible monoprotic acid HA. HA ? H(+) + A(-) at t=0 C 0 0 at eq. C(a million-x) Cx Cx Now, [HA] initially is C(=0.174 M). If 'x' is the degree of dissociation of acid, at equilibrium, [HA] remaining will be C-Cx, i.e. C(a million-x), and [H(+)] & [A(-)] shaped should be Cx. Now, Ka = [A(-)][H(+)]/[HA] => Ka = Cx²/(a million-x) Now, on condition that Ka = 2.5×10^-3 and for on account that answer is dilute, we may be able to approximate (a million-x) as a million. therefore, inducing the above reported consequences and value of C as 0.174M, we get 2.5×10^-3 = 0.174x² => x ? 0.11987 therefore, % ionisation = 11.987% ? 12% it is also possible to analyze the end result by utilizing no longer utilizing the approximation. if so a quadratic equation will be shaped. you receives 2 roots, one helpful and one unfavourable. forget the unfavourable one. by utilizing that technique, you get x ? 0.1129