I am doing a lab and I am calculating an experimental value for it from the slope of my data. I just wanted to know if there was a theoretical value for it or is it different depending on the situation.
If it is any help the wavelength at which it absorbs the most light is 510 nm.
Please site sources or how you got it so I can refer to it in my lab.
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There is a figure in the textbook "Advanced Inorganic Chemistry", by Cotton and Wilkinson, 5th edition (and perhaps the 6th, but I don't have access to that) that shows the electronic absorption spectrum of the Co(H₂O)₆²⁺ ion (which is the species you're observing if the λmax is 510 nm). A very recent measurement appears in a journal article (Inorg. Chem., 2012, 51, 4850-54 – Figure 2). The molar absorptivity at 510 is approximately 5 M⁻¹ cm⁻¹. The absorption is weak because Co(H₂O)₆²⁺ has a center of symmetry and d-d transitions are dipole forbidden for centrosymmetric complexes. In the figure I cited, you'll see that the unusual tetrahedral complex Co(H₂O)₄²⁺ (that's why it was published) has a molar absorptivity about 100 times stronger (marked [emim]BF₄ in the figure) because it is tetrahedral and has no center of symmetry.
If you look up the article (you'll need to be at a location where you can get free access - on campus at a college or university), you should be able to confirm that the spectrum to which I'm referring looks like yours.
EDIT: I put a screen shot of the figure I cited in the link below. The pink line is the Co(H₂O)₆²⁺ spectrum (Note: × 100 !) and the black is the the unusual tetrahedral complex Co(H₂O)₄²⁺.
Hello fellow IB Chemistry Student.
The molar absorptivity is the slope of the line, if you graph Absorption vs. Molarity. I got 4.97M-1cm-1.