ΔG∘rxn = ?
E∘cell = ?
Answer
Part 1
∆G° = –RTlnK = –(8.314 J/mol-K)*(298 K)*ln(5.7 × 10-2) =
T = 298 k
R= 8.314 J/mol-K
this equals to, ∆G° = [ -8.314*298*2.303*(-2)*log57 ] / 1000 = 20.03 kj/mol
Part 2
ΔG = -nFEcell
where
ΔG is the free energy of the reaction
n is the number of moles of electrons exchanged in the reaction
F is Faraday's constant (96484.56 C/mol)
E0 is the cell potential.
E0 = - ∆G°/2F = - 20.03 kj/mol /2* (96,485 C/mol )
this equals to - 0.1036 ( j / coulomb) = - 0.1036 v
1 faraday = 96 485 coulombs
1 joule per coulomb is equivalent to 1 volt.
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Verified answer
Answer
Part 1
∆G° = –RTlnK = –(8.314 J/mol-K)*(298 K)*ln(5.7 × 10-2) =
T = 298 k
R= 8.314 J/mol-K
this equals to, ∆G° = [ -8.314*298*2.303*(-2)*log57 ] / 1000 = 20.03 kj/mol
Part 2
ΔG = -nFEcell
where
ΔG is the free energy of the reaction
n is the number of moles of electrons exchanged in the reaction
F is Faraday's constant (96484.56 C/mol)
E0 is the cell potential.
E0 = - ∆G°/2F = - 20.03 kj/mol /2* (96,485 C/mol )
this equals to - 0.1036 ( j / coulomb) = - 0.1036 v
1 faraday = 96 485 coulombs
1 joule per coulomb is equivalent to 1 volt.