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Even if you are in another country, your PS3 will go to the PSN Store that your account is associated with. I can access the UK store only by creating a UK account (I live in the US). My current PSN ID will always connect to the North American PSN Store, even if I am in Europe, Asia, Japan, etc.

You shouldn't have any trouble with the DLC as they should be exactly the same. If you plan on buying the games in London, the only problem you may have is a video problem, as London is PAL, and your (I would assume) North American PS3 is NTSC. As long as you use an HDMI cable, you won't have any problem. Any other cable may give you issues.

If you are moving to London, then create a new account that has the London address, and use it to download DLC (if you have a problem). Once it is downloaded, any PSN ID can use the content, as long as the PSN ID associated with the content is still on the PS3.

If you are just going to visit London, and will go back to Brazil, then I would get the NTSC (North America) game, not the PAL (Europe) game.

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